دورية أكاديمية

The apparent variability of silkworm (Bombyx mori) silk and its relationship with degumming

التفاصيل البيبلوغرافية
العنوان: The apparent variability of silkworm (Bombyx mori) silk and its relationship with degumming
المؤلفون: Perea, Gracia Belén, Solanas, Concepción, Marí-Buyé, Núria, Madurga, Rodrigo, Agulló Rueda, F., Muinelo, Alfonso, Riekel, Christian, Burghammer, Manfred, Jorge, Inmaculada, Vázquez, Jesús, Plaza, Gustavo R., Torres, Adriana L., Pozo, Francisco de, Guinea, Guinea V., Elices, Manuel, Cenis, José Luis, Pérez-Rigueiro, José
المساهمون: Comunidad de Madrid, Ministerio de Economía y Competitividad (España), Fundación Botín, Banco Santander
بيانات النشر: Elsevier
سنة النشر: 2016
المجموعة: Digital.CSIC (Consejo Superior de Investigaciones Científicas / Spanish National Research Council)
مصطلحات موضوعية: Biomimetics, X-ray diffraction, Raman spectroscopy, Mechanical characterization, Silk
الوصف: As spun silkworm (Bombyx mori) silk fibers were compared in terms of their tensile behavior and microstructure with fibers subjected to different degumming treatments. Fibers were initially retrieved by forced silking directly from the worms and, either characterized in the as spun condition, or subjected to one of the following treatments: immersion in water, conventional degumming or degumming under longitudinally constrained conditions. Microstructure was assessed by X-ray diffraction and Raman spectroscopy. In addition, polyacrylamide gel electrophoresis was used to determine the influence of degumming on silk at a molecular level. Our study not only shows that degumming represents a major contribution to the accepted idea of silkworm silk as a highly variable material, but also provides new insights in the relationship between microstructure and tensile behavior in these fibers. In particular, it is shown that the arrangement of the hydrogen bond network in fibers subjected to different treatments plays a critical role in determining the mechanical behavior of silkworm silk. ; The work was funded by Ministerio de Economía y Competitividad (Spain) through projects MAT2012-38412-C02-01 and DPI2013-46485, by the Comunidad de Madrid (Spain) (Grant S2011/BMD-2460) and by Fundación Marcelino Botín and by Banco Santander through its Santander Universities Global Division. MINECO/ICTI2013-2016/DPI2013-46485
نوع الوثيقة: article in journal/newspaper
اللغة: unknown
تدمد: 0014-3057
العلاقة: #PLACEHOLDER_PARENT_METADATA_VALUE#; S2011/BMD-2460; https://doi.org/10.1016/j.eurpolymj.2016.03.012Test; Sí; European Polymer Journal 78: 129-140 (2016); http://hdl.handle.net/10261/186200Test; http://dx.doi.org/10.13039/100012818Test; http://dx.doi.org/10.13039/501100003329Test; http://dx.doi.org/10.13039/501100006373Test; http://dx.doi.org/10.13039/100010784Test
DOI: 10.1016/j.eurpolymj.2016.03.012
DOI: 10.13039/100012818
DOI: 10.13039/501100003329
DOI: 10.13039/501100006373
DOI: 10.13039/100010784
الإتاحة: https://doi.org/10.1016/j.eurpolymj.2016.03.012Test
https://doi.org/10.13039/100012818Test
https://doi.org/10.13039/501100003329Test
https://doi.org/10.13039/501100006373Test
https://doi.org/10.13039/100010784Test
http://hdl.handle.net/10261/186200Test
حقوق: none
رقم الانضمام: edsbas.EBBAF08
قاعدة البيانات: BASE
الوصف
تدمد:00143057
DOI:10.1016/j.eurpolymj.2016.03.012