دورية أكاديمية
The apparent variability of silkworm (Bombyx mori) silk and its relationship with degumming
العنوان: | The apparent variability of silkworm (Bombyx mori) silk and its relationship with degumming |
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المؤلفون: | Perea, Gracia Belén, Solanas, Concepción, Marí-Buyé, Núria, Madurga, Rodrigo, Agulló Rueda, F., Muinelo, Alfonso, Riekel, Christian, Burghammer, Manfred, Jorge, Inmaculada, Vázquez, Jesús, Plaza, Gustavo R., Torres, Adriana L., Pozo, Francisco de, Guinea, Guinea V., Elices, Manuel, Cenis, José Luis, Pérez-Rigueiro, José |
المساهمون: | Comunidad de Madrid, Ministerio de Economía y Competitividad (España), Fundación Botín, Banco Santander |
بيانات النشر: | Elsevier |
سنة النشر: | 2016 |
المجموعة: | Digital.CSIC (Consejo Superior de Investigaciones Científicas / Spanish National Research Council) |
مصطلحات موضوعية: | Biomimetics, X-ray diffraction, Raman spectroscopy, Mechanical characterization, Silk |
الوصف: | As spun silkworm (Bombyx mori) silk fibers were compared in terms of their tensile behavior and microstructure with fibers subjected to different degumming treatments. Fibers were initially retrieved by forced silking directly from the worms and, either characterized in the as spun condition, or subjected to one of the following treatments: immersion in water, conventional degumming or degumming under longitudinally constrained conditions. Microstructure was assessed by X-ray diffraction and Raman spectroscopy. In addition, polyacrylamide gel electrophoresis was used to determine the influence of degumming on silk at a molecular level. Our study not only shows that degumming represents a major contribution to the accepted idea of silkworm silk as a highly variable material, but also provides new insights in the relationship between microstructure and tensile behavior in these fibers. In particular, it is shown that the arrangement of the hydrogen bond network in fibers subjected to different treatments plays a critical role in determining the mechanical behavior of silkworm silk. ; The work was funded by Ministerio de Economía y Competitividad (Spain) through projects MAT2012-38412-C02-01 and DPI2013-46485, by the Comunidad de Madrid (Spain) (Grant S2011/BMD-2460) and by Fundación Marcelino Botín and by Banco Santander through its Santander Universities Global Division. MINECO/ICTI2013-2016/DPI2013-46485 |
نوع الوثيقة: | article in journal/newspaper |
اللغة: | unknown |
تدمد: | 0014-3057 |
العلاقة: | #PLACEHOLDER_PARENT_METADATA_VALUE#; S2011/BMD-2460; https://doi.org/10.1016/j.eurpolymj.2016.03.012Test; Sí; European Polymer Journal 78: 129-140 (2016); http://hdl.handle.net/10261/186200Test; http://dx.doi.org/10.13039/100012818Test; http://dx.doi.org/10.13039/501100003329Test; http://dx.doi.org/10.13039/501100006373Test; http://dx.doi.org/10.13039/100010784Test |
DOI: | 10.1016/j.eurpolymj.2016.03.012 |
DOI: | 10.13039/100012818 |
DOI: | 10.13039/501100003329 |
DOI: | 10.13039/501100006373 |
DOI: | 10.13039/100010784 |
الإتاحة: | https://doi.org/10.1016/j.eurpolymj.2016.03.012Test https://doi.org/10.13039/100012818Test https://doi.org/10.13039/501100003329Test https://doi.org/10.13039/501100006373Test https://doi.org/10.13039/100010784Test http://hdl.handle.net/10261/186200Test |
حقوق: | none |
رقم الانضمام: | edsbas.EBBAF08 |
قاعدة البيانات: | BASE |
تدمد: | 00143057 |
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DOI: | 10.1016/j.eurpolymj.2016.03.012 |