دورية أكاديمية

Modified Method for Bentonite Purification and Characterization; a Case Study Using Bentonite from Tsunagi Mine, Niigata, Japan

التفاصيل البيبلوغرافية
العنوان: Modified Method for Bentonite Purification and Characterization; a Case Study Using Bentonite from Tsunagi Mine, Niigata, Japan
المؤلفون: Hayakawa, Takayuki, Minase, Makoto, Fujita, Ken-Ichi, Ogawa, Makoto
المصدر: Clays and Clay Minerals ; volume 64, issue 3, page 275-282 ; ISSN 0009-8604 1552-8367
بيانات النشر: Cambridge University Press (CUP)
سنة النشر: 2016
الوصف: A modified procedure for bentonite purification and a new method for the quantitative characterization of bentonite using smectite content are reported. Bentonite found in a drill core of Tsunagi Mine, Niigata, Japan was evaluated by the new method to demonstrate the substantial increase in smectite content from 40% in the original bentonite to 75% after purification using a new procedure. Powder samples were prepared by putting blocks of bentonite into acetone to remove water without mechanical crushing. The powdered, acetone-dried bentonite was purified by a dispersion-sedimentation method in water after cation exchange of the interlayer Ca 2+ ion with Na + ion by the reaction of raw bentonite with aqueous NaCl. The purification was evaluated using X-ray diffraction and thermogravimetric analyses (TG). The raw bentonite contained feldspar, quartz, and cristobalite, and feldspar and quartz were removed by the new purification procedure. The purification was evaluated quantitatively by comparing the TG data before and after the purification. The purified bentonite swelled in water to give a stable aqueous suspension and 3 g of purified bentonite dispersed in 60 mL of water was stable for several days. The replacement of interlayer sodium with dibehenyldimethylammonium gave an organophilic clay, which swelled in toluene. The bentonite has potential practical uses as a purified bentonite and an organophilic bentonite.
نوع الوثيقة: article in journal/newspaper
اللغة: English
DOI: 10.1346/ccmn.2016.0640303
الإتاحة: https://doi.org/10.1346/ccmn.2016.0640303Test
https://www.cambridge.org/core/services/aop-cambridge-core/content/view/S0009860400038945Test
حقوق: https://www.cambridge.org/core/termsTest
رقم الانضمام: edsbas.236206BB
قاعدة البيانات: BASE