دورية أكاديمية
An integrated photocatalytic/enzymatic system for the reduction of CO2 to methanol in bioglycerol–water
| العنوان: | An integrated photocatalytic/enzymatic system for the reduction of CO2 to methanol in bioglycerol–water |
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| المؤلفون: | Michele Aresta, Angela Dibenedetto, Tomasz Baran, Antonella Angelini, Przemysław Łabuz, Wojciech Macyk |
| المصدر: | Beilstein Journal of Organic Chemistry, Vol 10, Iss 1, Pp 2556-2565 (2014) |
| بيانات النشر: | Beilstein-Institut, 2014. |
| سنة النشر: | 2014 |
| المجموعة: | LCC:Science LCC:Organic chemistry |
| مصطلحات موضوعية: | CO2 chemistry, electron transfer, enzymatic CO2 reduction, NADH regeneration, photochemistry, photosensitization, Science, Organic chemistry, QD241-441 |
| الوصف: | A hybrid enzymatic/photocatalytic approach for the conversion of CO2 into methanol is described. For the approach discussed here, the production of one mol of CH3OH from CO2 requires three enzymes and the consumption of three mol of NADH. Regeneration of the cofactor NADH from NAD+ was achieved by using visible-light-active, heterogeneous, TiO2-based photocatalysts. The efficiency of the regeneration process is enhanced by using a Rh(III)-complex for facilitating the electron and hydride transfer from the H-donor (water or a water–glycerol solution) to NAD+. This resulted in the production of 100 to 1000 mol of CH3OH from one mol of NADH, providing the possibility for practical application. |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English |
| تدمد: | 1860-5397 |
| العلاقة: | https://doaj.org/toc/1860-5397Test |
| DOI: | 10.3762/bjoc.10.267 |
| الوصول الحر: | https://doaj.org/article/aa863b5dccc240e3ac9cf814b9529bf3Test |
| رقم الانضمام: | edsdoj.863b5dccc240e3ac9cf814b9529bf3 |
| قاعدة البيانات: | Directory of Open Access Journals |
Full Text Finder | تدمد: | 18605397 |
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| DOI: | 10.3762/bjoc.10.267 |