التفاصيل البيبلوغرافية
| العنوان: |
Electronic ground state of Ni2+ |
| المؤلفون: |
Zamudio-Bayer, V., Lindblad, R., Bülow, C., Leistner, G., Terasaki, A., v. Issendorff, B., Lau, J. T. |
| المساهمون: |
Genesis Research Institute, Toyota Technological Institute, Bundesministerium für Bildung und Forschung, Vetenskapsrådet |
| المصدر: |
The Journal of Chemical Physics ; volume 145, issue 19 ; ISSN 0021-9606 1089-7690 |
| بيانات النشر: |
AIP Publishing |
| سنة النشر: |
2016 |
| الوصف: |
The Φ9/24 ground state of the Ni2+ diatomic molecular cation is determined experimentally from temperature and magnetic-field-dependent x-ray magnetic circular dichroism spectroscopy in a cryogenic ion trap, where an electronic and rotational temperature of 7.4±0.2 K was reached by buffer gas cooling of the molecular ion. The contribution of the spin dipole operator to the x-ray magnetic circular dichroism spin sum rule amounts to 7Tz=0.17±0.06μB per atom, approximately 11% of the spin magnetic moment. We find that, in general, homonuclear diatomic molecular cations of 3d transition metals seem to adopt maximum spin magnetic moments in their electronic ground states. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
English |
| DOI: |
10.1063/1.4967821 |
| DOI: |
10.1063/1.4967821/13587478/194302_1_online.pdf |
| الإتاحة: |
https://doi.org/10.1063/1.4967821Test |
| رقم الانضمام: |
edsbas.B1575612 |
| قاعدة البيانات: |
BASE |
