The Influence of the Solvent on the Rates of Chain Propagation and Termination Reactions in Radical Polymerisation
| العنوان: | The Influence of the Solvent on the Rates of Chain Propagation and Termination Reactions in Radical Polymerisation |
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| المؤلفون: | Gromov Vladimir F, P.M. Khomikovskii |
| المصدر: | Russian Chemical Reviews. 48:1040-1054 |
| بيانات النشر: | Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1979. |
| سنة النشر: | 1979 |
| مصطلحات موضوعية: | Reaction rate, Solvent, chemistry.chemical_compound, Chain propagation, Monomer, chemistry, Polymerization, Aqueous medium, Polymer chemistry, Polar, General Chemistry |
| الوصف: | The influence of the solvent on the rate of radical polymerisation and copolymerisation, observed and investigated in the last ten years and caused mainly by a change in the rate of the elementary chain propagation reaction, is discussed. The published data on the polymerisation and copolymerisation of a number of monomers in solvents of different types are surveyed. Attention is drawn to the fact that the greatest effects are observed for polar monomers, particularly for water-soluble monomers in an aqueous medium. The causes of the change in the overall rate of reaction, the constants kp, and the copolymerisation constants for different monomers are examined. The bibliography includes 104 references. |
| تدمد: | 1468-4837 0036-021X |
| الوصول الحر: | https://explore.openaire.eu/search/publication?articleId=doi_________::9ac3ca1794270a634f2ee6b727e426d7Test https://doi.org/10.1070/rc1979v048n11abeh002428Test |
| رقم الانضمام: | edsair.doi...........9ac3ca1794270a634f2ee6b727e426d7 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 14684837 0036021X |
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