دورية أكاديمية
SCOPE OF VARIOUS SOLVENTS AND THEIR EFFECTS ON SOLVOTHERMAL SYNTHESIS OF Ni-BTC
| العنوان: | SCOPE OF VARIOUS SOLVENTS AND THEIR EFFECTS ON SOLVOTHERMAL SYNTHESIS OF Ni-BTC |
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| المؤلفون: | Farrukh Israr, Duk Kyung Kim, Yeongmin Kim, Wongee Chun |
| المصدر: | Química Nova, Vol 39, Iss 6, Pp 669-675 (2016) |
| بيانات النشر: | Sociedade Brasileira de Química, 2016. |
| سنة النشر: | 2016 |
| المجموعة: | LCC:Chemistry |
| مصطلحات موضوعية: | Ni-BTC MOF, different solvent conditions, bases, different BETs, Chemistry, QD1-999 |
| الوصف: | Ni-BTC (BTC = 1,3,5-benzene tricarboxylate) metal organic framework (MOF) was synthesized using different solvent conditions. Solvent mixtures of water/N,N-dimethylformamide (DMF), water/ethanol, and water/ethanol/DMF were used for the reactions with or without a variety of bases at 160 ºC for 48 hours. Even with same green crystals, prepared MOFs show all different BET surface areas and different XRD patterns. The highest BET surface area of the crystals was 850 m2/g obtained from water/DMF solvent with NH4OH as a base. The measured surface areas of the crystals follows the order of Ni-BTC(water/DMF-NH4OH) > Ni-BTC(water/DMF-TMA) > Ni-BTC(water/DMF) > Ni-BTC(water/DMF-Pyridine)> Ni-BTC(water/ethanol)> Ni-BTC(water/DMF-aniline)> Ni-BTC(water/DMF-NaOH). |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English Spanish; Castilian Portuguese |
| تدمد: | 1678-7064 0100-4042 |
| العلاقة: | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422016000600669&lng=en&tlng=enTest; https://doaj.org/toc/1678-7064Test |
| DOI: | 10.5935/0100-4042.20160068 |
| الوصول الحر: | https://doaj.org/article/61e5ec001ccd4499aa9394ff7f86ca83Test |
| رقم الانضمام: | edsdoj.61e5ec001ccd4499aa9394ff7f86ca83 |
| قاعدة البيانات: | Directory of Open Access Journals |
Full Text Finder | تدمد: | 16787064 01004042 |
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| DOI: | 10.5935/0100-4042.20160068 |