دورية أكاديمية

Gamma Radiation Induced Degradation and Leaching Behavior of Ion Exchange Resin

التفاصيل البيبلوغرافية
العنوان: Gamma Radiation Induced Degradation and Leaching Behavior of Ion Exchange Resin
المؤلفون: Wang Kyu Choi, Seung Joo Lim
المصدر: 대한환경공학회지, Vol 44, Iss 10, Pp 366-374 (2022)
بيانات النشر: Korean Society of Environmental Engineers, 2022.
سنة النشر: 2022
المجموعة: LCC:Environmental engineering
مصطلحات موضوعية: gamma irradiation, ion exchange resin, degradation, nuclide, leaching behavior, Environmental engineering, TA170-171
الوصف: Objectives The objectives of this study were to investigate gamma radiation induced degradation and leaching behavior of nuclide and/or organic complexing agent adsorbed ion exchange resin. Methods Cation exchange resin (IRN 77) and anion exchange resin (IRN 78) widely used in nuclear power plants were purchased. Cobalt ion and EDTA were used to represent nuclide and organic complexing agent adsorbed to ion exchange resins. Cation and anion exchange resin adsorbed cobalt ion and/or EDTA were radiated by 60Co nuclide. The radiation dose rate was 10 kGy/hr and total doses were 0, 300, 500, and 700 kGy. Results and Discussion The sulfone and quaternary ammonium functional groups of gamma radiated ion exchange resin were degraded, indicating nuclide/organic complexing agent would be leached from ion exchange resin. It was shown that degradation of anion exchange resin was worse than that of cation exchange resin. While the high concentrations of cobalt ion and organic matter were observed in leachate from anion exchange resin, those in leachate from cation exchange resin were very low. For mixed cation and anion exchange resin, the leaching behavior of mixed resin was improved. This shows that disposal in the form of a mixed ion exchange resin was evaluated as a safer method than that of a cation or anion exchange resin alone. Conclusion The adsorbed nuclide and organic complexing agent were leached from ion exchange resin by gamma irradiation. The leaching behavior of cation and anion exchange resin was improved by using mixed ion exchange resin.
نوع الوثيقة: article
وصف الملف: electronic resource
اللغة: English
Korean
تدمد: 1225-5025
2383-7810
العلاقة: http://www.jksee.or.kr/upload/pdf/KSEE-2022-44-10-366.pdfTest; https://doaj.org/toc/1225-5025Test; https://doaj.org/toc/2383-7810Test
DOI: 10.4491/KSEE.2022.44.10.366
الوصول الحر: https://doaj.org/article/a97b65ef74e04d76b8ae25c783781607Test
رقم الانضمام: edsdoj.97b65ef74e04d76b8ae25c783781607
قاعدة البيانات: Directory of Open Access Journals
الوصف
تدمد:12255025
23837810
DOI:10.4491/KSEE.2022.44.10.366