Dichlorido{N′-[(pyridin-2-yl)methyl­idene-κN]acetohydrazide-κ2 N′,O}copper(II)

التفاصيل البيبلوغرافية
العنوان: Dichlorido{N′-[(pyridin-2-yl)methyl­idene-κN]acetohydrazide-κ2 N′,O}copper(II)
المؤلفون: Shiann Cherng Sheu, Pei Hsin Liu, Jui-Hsien Huang, Amitabha Datta
المصدر: Acta Crystallographica Section E: Structure Reports
بيانات النشر: International Union of Crystallography, 2011.
سنة النشر: 2011
مصطلحات موضوعية: Metal-Organic Papers, Hydrogen bond, Chemistry, Ligand, chemistry.chemical_element, General Chemistry, Condensed Matter Physics, Bioinformatics, Chloride, Copper, Crystal, Crystallography, medicine, General Materials Science, medicine.drug, Coordination geometry
الوصف: In the title compound, [CuCl(2)(C(8)H(9)N(3)O)], the Cu(II) atom has a distorted square-pyramidal CuCl(2)N(2)O coordination geometry. The tridentate acetohydrazide ligand occupies three basal positions, the fourth basal position being defined by a chloride anion at a distance of 2.2116 (6) Å. The second chloride anion is in the apical position and forms a longer Cu-Cl distance of 2.4655 (7) Å. Inter-molecular N-H⋯Cl hydrogen bonds are present in the crystal, leading to the formation of chains along [10[Formula: see text]].
اللغة: English
تدمد: 1600-5368
الوصول الحر: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9b29356c5de0a9b682a24a3c7f3590d7Test
http://europepmc.org/articles/PMC3238746Test
حقوق: OPEN
رقم الانضمام: edsair.doi.dedup.....9b29356c5de0a9b682a24a3c7f3590d7
قاعدة البيانات: OpenAIRE