Stereospecific Synthesis of the α- and β-d -Glucopyranosyl Ureas
| العنوان: | Stereospecific Synthesis of the α- and β- |
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| المؤلفون: | Yoshiyasu Ichikawa, Taihei Nishiyama, Minoru Isobe |
| المصدر: | The Journal of Organic Chemistry. 66:4200-4205 |
| بيانات النشر: | American Chemical Society (ACS), 2001. |
| سنة النشر: | 2001 |
| مصطلحات موضوعية: | Stereospecificity, Stereochemistry, Chemistry, Organic Chemistry |
| الوصف: | A new, one-pot, two-stage procedure for the preparation of the α- and β-d-glucopyranosyl ureas has been developed. Oxidation of glucopyranosyl isocyanides provides glucopyranosyl isocyanates, which can be trapped in situ with amines to afford good yields of glucopyranosyl ureas. Application of this method establishes the successful synthesis of the hitherto unknown N,N‘-di-α,α- and α,β-d-glucopyranosyl ureas. |
| تدمد: | 1520-6904 0022-3263 |
| الوصول الحر: | https://explore.openaire.eu/search/publication?articleId=doi_________::9417c1a406cc81a64d496bbe98720767Test https://doi.org/10.1021/jo0100751Test |
| رقم الانضمام: | edsair.doi...........9417c1a406cc81a64d496bbe98720767 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 15206904 00223263 |
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