دورية أكاديمية

A Simple and Convenient Method for the Synthesis of N,N-Diaryl Tertiary Amines.

التفاصيل البيبلوغرافية
العنوان: A Simple and Convenient Method for the Synthesis of N,N-Diaryl Tertiary Amines.
المؤلفون: Wekesa, Francis S., Phadke, Neha, Jahier, Claire, Cordes, David B., Findlater, Michael
المصدر: Synthesis; 2014, Vol. 46 Issue 8, p1046-1051, 6p
مصطلحات موضوعية: TERTIARY amines, ETHYLAMINES, ALKYLATION, AROMATIC amines, TRANSITION metal catalysts, FUNCTIONAL groups
مستخلص: Direct preparation of tertiary amines in which two substituents are aromatic is described. In the presence of either the inorganic base sodium tert-butoxide or the sterically hindered organic base diisopropylethylamine, the alkylation of secondary diarylamines is achieved smoothly. In contrast to methods previously reported in the literature, this procedure is high-yielding and does not require the use of transition-metal catalysts or functional-group-intolerant hydride reductants. [ABSTRACT FROM AUTHOR]
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قاعدة البيانات: Complementary Index
الوصف
تدمد:00397881
DOI:10.1055/s-0033-1340820