Synthesis, structure and spectroscopic characterization of a new organic cation diphosphate: [2,6-(C2H5)2C6H3NH3]2H2P2O7 · 2H2O
| العنوان: | Synthesis, structure and spectroscopic characterization of a new organic cation diphosphate: [2,6-(C2H5)2C6H3NH3]2H2P2O7 · 2H2O |
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| المؤلفون: | M. Rzaigui, S. Akriche |
| المصدر: | Structural Chemistry. 19:827-831 |
| بيانات النشر: | Springer Science and Business Media LLC, 2008. |
| سنة النشر: | 2008 |
| مصطلحات موضوعية: | Hydrogen bond, Chemistry, Intermolecular force, Infrared spectroscopy, Crystal structure, Condensed Matter Physics, Chemical synthesis, symbols.namesake, Crystallography, X-ray crystallography, symbols, Physical and Theoretical Chemistry, van der Waals force, Monoclinic crystal system |
| الوصف: | The chemical preparation, crystal structure and spectroscopic characterization of [2,6-(C2H5)2C6H3NH3]2H2P2O7 · 2H2O have been reported. The compound crystallizes in the monoclinic system in space group P21/c and cell parameters a = 14.323(2), b = 11.158(3), c = 16.387(2) A and β = 96.34(3)°; V = 2602.8(9) A3 and Z = 4. Crystal structure has been determined and refined to R = 0.044, using 3528 independent reflections. The atomic arrangement of the title compound shows anionic layer of formulae [H2P2O7(H2O)2] n 2n− stacked along the c-axis. The 2,6-diethylanilinium cations establish on both sides of these inorganic layer hydrogen bonds so as to contribute to the intralayer cohesion in the network. The different building species are held together by means of O–H···O and N–H···O intermolecular hydrogen bonds in addition to electrostatic and van der Waals interactions. |
| تدمد: | 1572-9001 1040-0400 |
| الوصول الحر: | https://explore.openaire.eu/search/publication?articleId=doi_________::5ea3fcef3bc2101550660c0c03d086d0Test https://doi.org/10.1007/s11224-008-9372-1Test |
| حقوق: | CLOSED |
| رقم الانضمام: | edsair.doi...........5ea3fcef3bc2101550660c0c03d086d0 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 15729001 10400400 |
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