دورية أكاديمية

Structure and microstructure of epitaxial SrnFenO3n-1 films.

التفاصيل البيبلوغرافية
العنوان: Structure and microstructure of epitaxial SrnFenO3n-1 films.
المؤلفون: Lebedev, O. I.1 oleg.lebedev@ua.ac.eb, Verbeeck, J.1, Van Tendeloo, G.1, N. Hayashi2, T. Terashima3, M. Nakano3
المصدر: Philosophical Magazine. 12/21/2004, Vol. 84 Issue 36, p3825-3841. 17p.
مصطلحات موضوعية: *IRON, *THIN films, *EPITAXY, *STRONTIUM ores, *STRONTIUM, *ELECTRON microscopy, *COPPER oxide, *METALLIC oxides, *PULSED laser deposition, *COATING processes
مستخلص: Thin films of SrFeO3-x (0≤x≤0.5) (SFO) grown on a (LaAlO3)0.3 SrAl0.5Ta0.5O3)0.7 (LSAT) substrate by pulsed laser deposition have been structurally investigated by electron diffraction and high resolution transmission electron microscopy for different post-deposition oxygen treatments. During the deposition and post-growth oxidation, the oxygen-reduced SFO films accept extra oxygen along the tetrahedral layers to minimize the elastic strain energy. The oxidation process stops at a concentration SFO2.875 and/or SFO2.75 because zero misfit with the LSAT substrate is reached. A possible growth mechanism and phase transition mechanism are suggested. The non-oxidized films exhibit twin boundaries having a local perovskite-type structure with a nominal composition close to SFO3. [ABSTRACT FROM AUTHOR]
قاعدة البيانات: Academic Search Index
الوصف
تدمد:14786435
DOI:10.1080/14786430412331313187