التفاصيل البيبلوغرافية
| العنوان: |
Nickel-Catalyzed Synthesis of Diarylamines via Oxidatively Induced C–N Bond Formation at Room Temperature. |
| المؤلفون: |
Ilies, Laurean1, Matsubara, Tatsuaki1, Nakamura, Eiichi1 |
| المصدر: |
Organic Letters. Vol. 14 Issue 21, p5570-5573. 4p. |
| مصطلحات موضوعية: |
*NICKEL catalysts, *CHEMICAL bonds, *OXIDATIVE coupling, *ORGANOMAGNESIUM compounds, *CHLORIDES, *KETONES, *DIAMINES |
| مستخلص: |
A nickel-catalyzed oxidative coupling of zinc amides with organomagnesium compounds selectively produces diarylamines under mild reaction conditions, with tolerance for chloride, bromide, hydroxyl, ester, and ketone groups. A diamine is bis-monoarylated. A bromoaniline undergoes N-arylation followed by Kumada–Tamao–Corriu coupling in one pot. The reaction may proceed via oxidatively induced reductive elimination of a nickel species. [ABSTRACT FROM AUTHOR] |
| قاعدة البيانات: |
Academic Search Index |
