Cajanusflavanols A–C, Three Pairs of Flavonostilbene Enantiomers from Cajanus cajan
| العنوان: | Cajanusflavanols A–C, Three Pairs of Flavonostilbene Enantiomers from Cajanus cajan |
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| المؤلفون: | Man-Mei Li, Wen-Cai Ye, Zhen-Long Wu, Qi-Fang He, Yuan-Lin Zhong, Ren-Wang Jiang, Yao-Lan Li, Xiao-Jun Huang, Ying Wang |
| المصدر: | Organic Letters. 20:876-879 |
| بيانات النشر: | American Chemical Society (ACS), 2018. |
| سنة النشر: | 2018 |
| مصطلحات موضوعية: | Molecular Structure, biology, 010405 organic chemistry, Chemistry, Stereochemistry, Organic Chemistry, Anti-Inflammatory Agents, Carbon skeleton, Stereoisomerism, 010402 general chemistry, biology.organism_classification, 01 natural sciences, Biochemistry, 0104 chemical sciences, Cajanus, Molecule, Physical and Theoretical Chemistry, Enantiomer |
| الوصف: | Three pairs of new flavonostilbene enantiomers, cajanusflavanols A-C (1-3), along with their putative biogenetic precursors 4-6, were isolated from Cajanus cajan. Compound 1 possesses an unprecedented carbon skeleton featuring a unique highly functionalized cyclopenta[1,2,3-de]isobenzopyran-1-one tricyclic core. Compounds 2 and 3 are the first examples of methylene-unit-linked flavonostilbenes. Their structures with absolute configurations were elucidated by spectroscopic analyses, X-ray diffraction, and computational calculations. Compounds 1 and 2 exhibited significant in vitro anti-inflammatory activities. |
| تدمد: | 1523-7052 1523-7060 |
| الوصول الحر: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3c180c2002ad720e79c33b2c7ea5029aTest https://doi.org/10.1021/acs.orglett.8b00010Test |
| رقم الانضمام: | edsair.doi.dedup.....3c180c2002ad720e79c33b2c7ea5029a |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 15237052 15237060 |
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