دورية أكاديمية

Exploring optoelectronic properties and excitation energy transfer mechanism in hybrid thin films of poly (N,N′-bis-4-butylphenyl- N,N′-bisphenyl)benzidine/fluorol 7GA.

التفاصيل البيبلوغرافية
العنوان: Exploring optoelectronic properties and excitation energy transfer mechanism in hybrid thin films of poly (N,N′-bis-4-butylphenyl- N,N′-bisphenyl)benzidine/fluorol 7GA.
المؤلفون: Al-Asbahi, Bandar Ali1 (AUTHOR) balasbahi@ksu.edu.sa
المصدر: Optical & Quantum Electronics. Jun2024, Vol. 56 Issue 6, p1-18. 18p.
مصطلحات موضوعية: *OPTOELECTRONICS, *CONJUGATED polymers, *ENERGY transfer, *FLUORESCENCE resonance energy transfer, *THIN films, *BENZIDINE, *HYBRID materials
الشركة/الكيان: INTERNATIONAL Commission on Illumination
مستخلص: This manuscript presents research on the optoelectronic and energy transfer properties of conjugated polymer poly (N,N′-bis-4-butylphenyl-N,N'-bisphenyl)benzidine (poly-TPD) and laser dye Fluorol 7GA (F7GA) hybrid thin films prepared via solution blending technique. Various weight ratios of F7GA were added to a fixed concentration of poly-TPD to form homogeneous hybrids. The hybrid thin films were characterized using absorption and photoluminescence spectroscopy. The results showed enhanced absorption, widened optical bandgaps, slight blue-shifted emission, and decreased refractive index in the hybrid films compared to pristine poly-TPD. The significant spectral overlap between the emission spectrum of poly-TPD and the absorption spectrum of F7GA, allowing for efficient Förster resonance energy transfer. Parameters including efficiency, distance, lifetime, and probability of energy transfer were calculated to quantitatively analyze energy transfer. Modulation of F7GA content led to tunable emission colors across the visible spectrum. Overall, the successful energy transfer demonstrated in this study paves the way for exciting future directions in the field of poly-TPD/F7GA hybrid materials for advanced optoelectronic applications. [ABSTRACT FROM AUTHOR]
قاعدة البيانات: Academic Search Index
الوصف
تدمد:03068919
DOI:10.1007/s11082-024-06826-5