دورية أكاديمية
Covalent Organic Framework with 3D Ordered Channel and Multi-Functional Groups Endows Zn Anode with Superior Stability
العنوان: | Covalent Organic Framework with 3D Ordered Channel and Multi-Functional Groups Endows Zn Anode with Superior Stability |
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المؤلفون: | Bin Li, Pengchao Ruan, Xieyu Xu, Zhangxing He, Xinyan Zhu, Liang Pan, Ziyu Peng, Yangyang Liu, Peng Zhou, Bingan Lu, Lei Dai, Jiang Zhou |
المصدر: | Nano-Micro Letters, Vol 16, Iss 1, Pp 1-14 (2024) |
بيانات النشر: | SpringerOpen, 2024. |
سنة النشر: | 2024 |
المجموعة: | LCC:Technology |
مصطلحات موضوعية: | Aqueous Zn ion batteries, Covalent organic framework, Interfacial modification, Zn ion flux regulation, Desolvation effect, Technology |
الوصف: | Highlights A fluorinated zincophilic covalent organic framework (COF-S-F) with sulfonic acid group (-SO3H) is prepared on the surface of Zn anode, which promotes the desolvation of hydrated Zn ions and inhibits the side reactions. The highly electronegative -F group in COF-S-F promotes fast and uniform transport of Zn ions along the interconnected channels, which contributes to the uniform electrodeposition process of Zn metal. Zn@COF-S-F symmetric cell achieves a superior stability of 1,000 h and Zn@COF-S-F|MnO2 cell delivers high specific capacity of 206.8 mAh g−1 at current density of 1.2 A g−1. |
نوع الوثيقة: | article |
وصف الملف: | electronic resource |
اللغة: | English |
تدمد: | 2311-6706 2150-5551 |
العلاقة: | https://doaj.org/toc/2311-6706Test; https://doaj.org/toc/2150-5551Test |
DOI: | 10.1007/s40820-023-01278-0 |
الوصول الحر: | https://doaj.org/article/7312b8c3678d440ab0f37817b21e7f43Test |
رقم الانضمام: | edsdoj.7312b8c3678d440ab0f37817b21e7f43 |
قاعدة البيانات: | Directory of Open Access Journals |
تدمد: | 23116706 21505551 |
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DOI: | 10.1007/s40820-023-01278-0 |