التفاصيل البيبلوغرافية
| العنوان: |
The Interface and Mechanical Properties of a CVD Single Crystal Diamond Produced by Multilayered Nitrogen Doping Epitaxial Growth. |
| المؤلفون: |
Zhao, Yun, Li, Chengming, Liu, Jinlong, An, Kang, Yan, Xiongbo, Hei, Lifu, Chen, Liangxian, Wei, Junjun, Lu, Fanxiu |
| المصدر: |
Materials (1996-1944); 8/1/2019, Vol. 12 Issue 15, p2492-2492, 1p, 6 Diagrams, 2 Charts, 3 Graphs |
| مصطلحات موضوعية: |
SINGLE crystals, MULTILAYERED thin films, DIAMOND crystals, CHEMICAL vapor deposition, X-ray topography, BUFFER layers, MICROWAVE plasmas, EPITAXY |
| مستخلص: |
In the present investigation, a nitrogen-doped multilayer homoepitaxial single crystal diamond is synthesized on a high-pressure high temperature (HPHT) Ib-type diamond substrate using the microwave plasma chemical vapor deposition (MPCVD) method. When 0.15 sccm of nitrogen was added in the gas phase, the growth rate of the doped layer was about 1.7 times that of the buffer layer, and large conical and pyramidal features are formed on the surface of the sample. Raman mapping and photoluminescence imaging of the polished cross sectional slice shows a broadband emission, with a characteristic zero phonon line (ZPL) at 575 nm in the doped layers, and large compressive stress was formed in the nitrogen-doped layers. X-ray topography shows that the defects at the interface can induce dislocation. The pyramid feature is formed at the defect, and more nitrogen-related defects are formed in the pyramid region. Thin nitrogen-doped multilayers were successfully prepared, and the thickness of the nitrogen-doped and buffer layers was about 650 nm each. The indentation measurements reveal that the thin nitrogen-doped multilayers are ultra-tough (at least ~22 MPa m1/2), compared to the Ib-type HPHT seed substrate (~8 MPa m1/2) and the unintentionally doped chemical vapor deposition (CVD) single crystal diamond (~14 MPa m1/2). [ABSTRACT FROM AUTHOR] |
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| قاعدة البيانات: |
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