Total assignment of the1H- and13C-NMR spectra of dinaphtho[1,2-b:1′,2′-d]thiophene through the concerted use of two-dimensional NMR techniques
| العنوان: | Total assignment of the1H- and13C-NMR spectra of dinaphtho[1,2-b:1′,2′-d]thiophene through the concerted use of two-dimensional NMR techniques |
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| المؤلفون: | Raymond N. Castle, Miguel Salazar, Diana K. Kruger, Gary E. Martin, Milton D. Johnston |
| المصدر: | Magnetic Resonance in Chemistry. 26:839-847 |
| بيانات النشر: | Wiley, 1988. |
| سنة النشر: | 1988 |
| مصطلحات موضوعية: | Analytical chemistry, General Chemistry, Nuclear magnetic resonance spectroscopy, Carbon-13 NMR, Spectral line, chemistry.chemical_compound, chemistry, Heteronuclear molecule, Thiophene, General Materials Science, Nuclear Experiment, Two-dimensional nuclear magnetic resonance spectroscopy, Heteronuclear single quantum coherence spectroscopy, Coherence (physics) |
| الوصف: | The 1H- and 13C-NMR spectra of dinaphtho[1,2-b:1′2′-d]thiophene (1), a sulfur-containing polynuclear heteroaromatic, have been totally assigned using a combination of two-dimensional NMR techniques. Techniques applied were standard proton-proton COSY, proton zero-quantum coherence (ZQCOSY, optimized to 7 Hz and to 1.75 Hz), proton double quantum coherence (DQCOSY, optimized to 7 Hz), broad-band decoupled (both dimensions) proton-carbon chemical shift correlation, long-range proton-carbon chemical shift correlation, and proton-carbon heteronuclear relayed coherence transfer. A comparison of these methods on 1 showed the most useful information concerning connectivities to be obtained from the zero-quantum coherence and long-range heteronuclear correlation experiments. A detailed critique of each type of experiment is given in the context of applications to polynuclear aromatics. |
| تدمد: | 1097-458X 0749-1581 |
| الوصول الحر: | https://explore.openaire.eu/search/publication?articleId=doi_________::e536494ce138c279abff303c9a4c587aTest https://doi.org/10.1002/mrc.1260261007Test |
| حقوق: | CLOSED |
| رقم الانضمام: | edsair.doi...........e536494ce138c279abff303c9a4c587a |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 1097458X 07491581 |
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