التفاصيل البيبلوغرافية
| العنوان: |
New oxidized sterols fromAspergillus awamoriand theendo-boat conformation adopted by the cyclohexene oxide system |
| المؤلفون: |
Nai-Li Wang, Xin-Sheng Yao, Jin-Shan Tang, Miao-Miao Jiang, Man-Mei Li, Yang Yu, Chuan-Xi Wang, Kui Hong, Hao Gao, Guo-Dong Chen |
| المصدر: |
Magnetic Resonance in Chemistry. 48:38-43 |
| بيانات النشر: |
Wiley, 2009. |
| سنة النشر: |
2009 |
| مصطلحات موضوعية: |
chemistry.chemical_compound, Stereochemistry, Chemistry, Cyclohexane conformation, Proton NMR, General Materials Science, General Chemistry, Carbon-13 NMR, Ring (chemistry), Two-dimensional nuclear magnetic resonance spectroscopy, Sterol, Aspergillus awamori, Cyclohexene oxide |
| الوصف: |
Two new oxidized sterols 1 and 2 were obtained from the active fraction of a mangrove fungus Aspergillus awamori isolated from the soils around the mangrove plant Acrostichum speciosum. Their structures were elucidated using spectroscopic methods as 22E-7α-methoxy-5α,6α-epoxyergosta-8(14),22-dien-3β-ol (1) and 22E-3β-hydroxy-5α,6α,8α,14α-diepoxyergosta-22-en-7-one (2). The NMR data and complete assignments for both DMSO-d6 and CDCl3 were given. Their cytotoxic activity against A549 cell line was evaluated. Furthermore, the detailed conformation analysis for ring B (cyclohexene oxide system) of sterol 1 was given on the basis of NOEs. The endo-boat conformation was considered as the preferred conformation for ring B rather than half-chair conformation. Copyright © 2009 John Wiley & Sons, Ltd. |
| تدمد: |
0749-1581 |
| الوصول الحر: |
https://explore.openaire.eu/search/publication?articleId=doi_________::179c962b84d78a2d9a7a80a1b293b183Test
https://doi.org/10.1002/mrc.2536Test |
| حقوق: |
CLOSED |
| رقم الانضمام: |
edsair.doi...........179c962b84d78a2d9a7a80a1b293b183 |
| قاعدة البيانات: |
OpenAIRE |
