التفاصيل البيبلوغرافية
| العنوان: |
Photochemical Study of Tris(benzotriazol-1-yl)methane. |
| المؤلفون: |
Androsov, Dmitry A.1, Neckers, Douglas C.1 neckers@photo.bgsu.edu |
| المصدر: |
Journal of Organic Chemistry. 2/16/2007, Vol. 72 Issue 4, p1148-1152. 5p. 2 Graphs. |
| مصطلحات موضوعية: |
*METHANE, *CHEMICAL decomposition, *BENZENE, *AMINES, *RADICALS (Chemistry), *PHOTOCHEMISTRY |
| مستخلص: |
Photodecomposition of tris(benzotrizol-1 -yl)methane (1) in benzene gives [1-benzotryazol-1 -yl-meth- ylidenej-biphenyl-2-ylamine (2) resulting from the loss of the benzotriazolyl radical and nitrogen followed by addition of benzene. Elimination of the second benzotriazolyl radical from 2 provides the biphenyl-2-ylmethyleneamine radical, which affords phenantridine (3) after ring closure. In contrast, the photolysis of 1 in methanol gives a high yield of benzotriazole (4). [ABSTRACT FROM AUTHOR] |
| قاعدة البيانات: |
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