دورية أكاديمية
An Environmental-friendly Procedure Based on Deep Eutectic Solvent for Extraction and Determination of Toxic Elements in Fish Species from Different Regions of Iraq
العنوان: | An Environmental-friendly Procedure Based on Deep Eutectic Solvent for Extraction and Determination of Toxic Elements in Fish Species from Different Regions of Iraq |
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المؤلفون: | Kalinaki Hanifar, Yasir Q. Almajidi, Hijran Sanaan Jabbar, Andrés Alexis Ramírez-Coronel, Farag M.A. Altalbawy, Abbas F. Almulla, Abduladheem Turki Jalil, Sameer A. Awad, Luis Andres Barboza-Arenas |
المصدر: | Journal of Food Protection, Vol 86, Iss 7, Pp 100102- (2023) |
بيانات النشر: | Elsevier, 2023. |
سنة النشر: | 2023 |
المجموعة: | LCC:Food processing and manufacture LCC:Nutrition. Foods and food supply |
مصطلحات موضوعية: | Deep eutectic solvent, Fish analysis, Liquid-phase microextraction, Toxic elements, Vortex assisted, Food processing and manufacture, TP368-456, Nutrition. Foods and food supply, TX341-641 |
الوصف: | In this study, an eco-friendly procedure was established by vortex-assisted liquid-phase microextraction based on deep eutectic solvent (VA−LPME−DES) combined with graphite furnace atomic absorption spectroscopy (GFAAS). The performance of this method was demonstrated by the extraction and analysis of lead (Pb), cadmium (Cd), and mercury (Hg) in fish samples. The hydrophobic DES is considered as a green extractant (environmentally friendly and less toxic than common organic solvents) and is a suitable alternative to common toxic organic solvents and is made of l-menthol and ethylene glycol (EG) with a molar ratio of 1:1. Under optimized conditions, the method linearity was in the ranges of 0.15–150 µg kg−1 with the coefficient of determinations (r2) higher than 0.996. Accordingly, the detection limits for Pb, Cd, and Hg were 0.05, 0.05, and 0.10 µg kg−1, respectively. The analysis of fish samples showed that the concentration of toxic elements in fish caught from the Tigris and Euphrates Rivers is much higher than the concentration of these elements in locally farmed trout fish. Also, the analysis of fish-certified reference materials with presented procedure produced results that were in good agreement with the certified values. The results showed that VA−LPME–DES is a very cheap, fast, and environmental-friendly procedure for the analysis of toxic elements in different types of fish species. |
نوع الوثيقة: | article |
وصف الملف: | electronic resource |
اللغة: | English |
تدمد: | 0362-028X |
العلاقة: | http://www.sciencedirect.com/science/article/pii/S0362028X23067741Test; https://doaj.org/toc/0362-028XTest |
DOI: | 10.1016/j.jfp.2023.100102 |
الوصول الحر: | https://doaj.org/article/d46ebe11b77f4904b759c14b88202406Test |
رقم الانضمام: | edsdoj.46ebe11b77f4904b759c14b88202406 |
قاعدة البيانات: | Directory of Open Access Journals |
تدمد: | 0362028X |
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DOI: | 10.1016/j.jfp.2023.100102 |