التفاصيل البيبلوغرافية
| العنوان: |
Two new halide-containing polyoxometalate-based compounds. |
| المؤلفون: |
Wang, La-Mei, Guo, Hai-Yang, Li, Su, Hu, Yang-Yang, Wang, Yan, Xiao, Li-Na, Zhao, De-Chuan, Gao, Zhong-Min, Zheng, Da-Fang, Cui, Xiao-Bing, Fan, Yong, Xu, Ji-Qing |
| المصدر: |
Journal of Coordination Chemistry; Feb2014, Vol. 67 Issue 4, p728-736, 9p |
| مصطلحات موضوعية: |
POLYOXOMETALATES, BIPYRIDINE, ANALYTICAL chemistry, MOLECULAR structure, LIGANDS (Chemistry) |
| مستخلص: |
Two new compounds, [CuCl(Phen)(H2O)][PW12O40][4,4′-H2bpy]·1.5H2O (1) and [Cd2(Phen)4Cl2][HPMo12O40](4,4′-bpy) (2) (bpy = bipyridine, Phen = phenanthroline), have been hydrothermally prepared and characterized by IR, UV–vis, XPS, XRD, elemental analysis, cyclic voltammetry analysis, and single-crystal X-ray diffraction analysis. Compound1exhibits a 1-D chain structure constructed from polyoxometalates (POMs) and transition metal complexes, whereas2presents a supramolecular structure constructed from POMs, metal halide clusters, and organic ligands. [ABSTRACT FROM AUTHOR] |
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| قاعدة البيانات: |
Complementary Index |
