دورية أكاديمية

Carbon vacancies and spatial confinement effects of VC-FCN0.3 prepared by spatial self-corrosion strategy achieved eco-friendly photocatalytic degradation to bisphenol F.

التفاصيل البيبلوغرافية
العنوان: Carbon vacancies and spatial confinement effects of VC-FCN0.3 prepared by spatial self-corrosion strategy achieved eco-friendly photocatalytic degradation to bisphenol F.
المؤلفون: Wang, Min1,2 (AUTHOR), Lu, Guanghua1,2 (AUTHOR) ghlu@hhu.edu.cn, Jiang, Runren1,2 (AUTHOR), Dang, Tianjian1,2 (AUTHOR), Chen, Yufang1,2 (AUTHOR), Liu, Jianchao1,2 (AUTHOR), Yan, Zhenhua1,2 (AUTHOR), Hou, Jun1,2 (AUTHOR)
المصدر: Journal of Cleaner Production. Apr2024, Vol. 447, pN.PAG-N.PAG. 1p.
مصطلحات موضوعية: PHOTODEGRADATION, NITRIDES, MASS transfer, VISIBLE spectra, CARBON, AIR purification, ECOSYSTEMS
مستخلص: The widespread use of bisphenol F (BPF) as the commonly used alternative to bisphenol A (BPA) in the industry and its hazardous effects on ecological system and human health have attracted widespread attention. In this study, V C -FCN 0.3 hollow nanotube structure with confinement space effects and combined carbon vacancies was constructed by the spatial self-corrosion strategy, which effectively addressed the inherent limitations of conventional carbon nitride and achieved 100% removal rate of BPF within 2 h under visible light. Carbon vacancies not only accelerated the transfer of photogenerated carriers, but also enhanced the adsorption and activation of oxygen that accelerating the production of ·O 2 −, the main active species in this system. In addition, the special spatial structure shortened the mass transfer distance between the target pollutants and the active species. What's more, V C -FCN 0.3 showed excellent, stable, and eco-friendly photocatalytic degradation of bisphenol F over a wide pH range and in five water matrices, contributing effectively to the solution of purification of wastewater containing bisphenol analogues. [Display omitted] • C 3 N 4 hollow tubes with V C were prepared by spatial self-corrosion strategy. • V C promoted light absorption, charge transport, O 2 adsorption and activation. • The unique structure as space confinement accelerated free radical activation. • V C -FCN 0.3 achieved eco-friendly photocatalytic degradation to bisphenol F. [ABSTRACT FROM AUTHOR]
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قاعدة البيانات: Business Source Index
الوصف
تدمد:09596526
DOI:10.1016/j.jclepro.2024.141545