دورية أكاديمية

Candidate membranes for the electrochemical salt-splitting of Sodium Sulfate.

التفاصيل البيبلوغرافية
العنوان: Candidate membranes for the electrochemical salt-splitting of Sodium Sulfate.
المؤلفون: Davis, Samuel M., Gray, Gary E., Kohl, Paul A.
المصدر: Journal of Applied Electrochemistry; Jun2008, Vol. 38 Issue 6, p777-783, 7p, 1 Diagram, 6 Charts, 1 Graph
مصطلحات موضوعية: ALKALI metals, SODIUM sulfate, SULFURIC acid, SODIUM hydroxide, CHEMICALS, ION-permeable membranes, ELECTROMAGNETIC fields, EXCHANGE reactions, CATIONS
مستخلص: This work examines the properties of selected cation and anion exchange membranes for use in the electrochemical separation of sodium sulfate into sodium hydroxide and sulfuric acid. The effect of membrane type, electrolyte composition and ion exchange membrane thickness on the current efficiency was investigated. A decrease in current efficiency was observed due to ion migration under the influence of the electric field, and, to a lesser extent, diffusional losses. Increasing the membrane thickness improves the current efficiency at the cost of higher power due to the higher cell potential. [ABSTRACT FROM AUTHOR]
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قاعدة البيانات: Complementary Index
الوصف
تدمد:0021891X
DOI:10.1007/s10800-008-9519-1