التفاصيل البيبلوغرافية
| العنوان: |
A 3D spin canted coordination polymer with in situ direct C[sbnd]H iodination of 1-H-tetrazole. |
| المؤلفون: |
Liu, Min-Min1 (AUTHOR), Sun, Long1 (AUTHOR), Yu, You-Zhu1 (AUTHOR), Wang, Ying-Xia1 (AUTHOR), Zhang, Xian-Ming1 (AUTHOR) zhangxm@dns.sxnu.edu.cn |
| المصدر: |
Inorganica Chimica Acta. Aug2019, Vol. 494, p74-77. 4p. |
| مصطلحات موضوعية: |
*IODINATION, *TETRAZOLES, *CUPRIC chloride, *COORDINATION polymers, *THERAPEUTICS |
| مستخلص: |
A 3D spin canted cupric MOF is constructed from the layered [Cu 2 Cl(tta) 2 ] n n− and chain-like [Cu(Itta)(I 0.25 tta) 2 ] n 2n− motifs linked by 5-Iodo-1- H -tetrazole from in situ C-H iodination of 1- H -tetrazole. • A novel 5- I -tetrazole based MOF has been prepared by the hydrothermal treatment of CuCl 2 , 1- H -tetrazole and HI acid. • The 5- I -tetrazole can be generated from the Direct C H in situ Iodination of 1- H -tetrazole. • The MOF exhibits spin canted antiferromagnetic couplings. Hydrothermal treatment of cupric chloride and tetrazole in the presence of hydroiodic acid generated a spin canted coordination polymer [Cu 3 (tta) 2 (Itta)(I 0.25 -tta) 2 Cl] (1), (Htta = 1- H -tetrazole, Itta = 5-Iodo-1- H -tetrazole), showing a 3D network constructed from layered [Cu 2 Cl(tta) 2 ] n n– and chain-like [Cu(Itta)(I 0.25 tta) 2 ] n 2n– moieties linked through expensive Itta groups in situ C H iodinated from cheap Htta. [ABSTRACT FROM AUTHOR] |
| قاعدة البيانات: |
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