دورية أكاديمية
Slurryless Li2S/Reduced Graphene Oxide Cathode Paper for High-Performance Lithium Sulfur Battery
العنوان: | Slurryless Li2S/Reduced Graphene Oxide Cathode Paper for High-Performance Lithium Sulfur Battery |
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المؤلفون: | Wang, Chao, Wang, Xusheng, Yang, Yuan, Kushima, Akihiro, Chen, Jitao, Huang, Yunhui, Li, Ju |
المساهمون: | Chen, JT (reprint author), Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China., Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China., MIT, Dept Nucl Sci & Engn, Cambridge, MA 02139 USA., MIT, Dept Mat Sci & Engn, Cambridge, MA 02139 USA., Huazhong Univ Sci & Technol, State Key Lab Mat Proc & Die & Mold Technol, Sch Mat Sci & Engn, Wuhan 430074, Hubei, Peoples R China., MIT, Dept Mech Engn, Cambridge, MA 02139 USA. |
المصدر: | EI ; PubMed ; SCI |
بيانات النشر: | nano letters |
سنة النشر: | 2015 |
المجموعة: | Peking University Institutional Repository (PKU IR) / 北京大学机构知识库 |
مصطلحات موضوعية: | Lithium sulfide, reduced graphene oxide paper, slurryless, flexible, nanoparticle, ION BATTERIES, COMPOSITE CATHODES, ENERGY, LI2S, MECHANISM, ANODES |
الوصف: | Lithium sulfide (Li2S) is a promising cathode material for LiS batteries with high capacity (theoretically 1166 mAh g(1)) and can be paired with nonlithiummetal anodes to avoid potential safety issues. However, the cycle life of coarse Li2S particles suffers from poor electronic conductivity and polysulfide shuttling. Here, we develop a flexible slurryless nano-Li2S/reduced graphene oxide cathode paper (nano-Li2S/rGO paper) by simple drop-coating. The Li2S/rGO paper can be directly used as a free-standing and binder-free cathode without metal substrate, which leads to significant weight savings. It shows excellent rate capability (up to 7 degrees C) and cycle life in coin cell tests due to the high electron conductivity, flexibility, and strong solvent absorbency of rGO paper. The Li2S particles that precipitate out of the solvent on rGO have diameters 2550 nm, which is in contrast to the 35 mu m coarse Li2S particles without rGO. ; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000351188000054&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701Test ; Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter ; SCI(E) ; EI ; PubMed ; 29 ; ARTICLE ; chenjitao@pku.edu.cn; huangyh@mail.hust.edu.cn; liju@mit.edu ; 3 ; 1796-1802 ; 15 |
نوع الوثيقة: | journal/newspaper |
اللغة: | English |
تدمد: | 1530-6984 1530-6992 |
العلاقة: | NANO LETTERS.2015,15,(3),1796-1802.; 650396; http://hdl.handle.net/20.500.11897/312538Test; WOS:000351188000054 |
DOI: | 10.1021/acs.nanolett.5600112 |
الإتاحة: | https://doi.org/20.500.11897/312538Test https://doi.org/10.1021/acs.nanolett.5600112Test https://hdl.handle.net/20.500.11897/312538Test |
رقم الانضمام: | edsbas.45208872 |
قاعدة البيانات: | BASE |
تدمد: | 15306984 15306992 |
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DOI: | 10.1021/acs.nanolett.5600112 |