Self-Assembly of Multidecker NiII Clusters from Preformed Ni4 Decks
| العنوان: | Self-Assembly of Multidecker NiII Clusters from Preformed Ni4 Decks |
|---|---|
| المؤلفون: | Cong-Min Ji, Hui-Juan Yang, Vassilis Tangoulis, Hui-Zhong Kou, Chongchao Zhao, Ai-Li Cui |
| المصدر: | Crystal Growth & Design. 9:4607-4609 |
| بيانات النشر: | American Chemical Society (ACS), 2009. |
| سنة النشر: | 2009 |
| مصطلحات موضوعية: | Crystallography, chemistry.chemical_compound, Nickel, Nuclear magnetic resonance, Spin states, chemistry, Basic solution, Pyridine, chemistry.chemical_element, General Materials Science, General Chemistry, Self-assembly, Condensed Matter Physics |
| الوصف: | In a basic solution of Ni(ClO4)2·6H2O and pyridine-2-amidoxime (H2pyaox), tetranuclear [Ni4(Hpyaox)2(pyaox)2]2+ fragments are formed that self-assemble to generate single-, double-, or triple-decker clusters [Ni4(Hpyaox)2(pyaox)2(Him)4](ClO4)2 (1), [Ni8(Hpyaox)4(pyaox)4(H2O)4](ClO4)2·H2O·CH3CN (2), [Ni12(Hpyaox)6(pyaox)6(H2O)2(N3)2](ClO4)4·8H2O·CH3CN (3). Magnetic studies show that the compounds possess high-spin ground states. |
| تدمد: | 1528-7505 1528-7483 |
| الوصول الحر: | https://explore.openaire.eu/search/publication?articleId=doi_________::c2b280f37ae160b9cf38909765421b16Test https://doi.org/10.1021/cg900975yTest |
| رقم الانضمام: | edsair.doi...........c2b280f37ae160b9cf38909765421b16 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 15287505 15287483 |
|---|