دورية أكاديمية
Single-Crystal and High-Resolution X-ray Diffraction Studies and Raman Spectrum of a Phosphorus(V) Chloride Complex Containing a Single Bromide Ion, P3Cl14Br
| العنوان: | Single-Crystal and High-Resolution X-ray Diffraction Studies and Raman Spectrum of a Phosphorus(V) Chloride Complex Containing a Single Bromide Ion, P3Cl14Br |
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| المؤلفون: | Gates, Peter N., Knachel, Howard, Finch, Arthur, Fratini, Albert, Fitch, Andrew N., Nardone, Ottavio, Otto, James C., Snider, Daniel A. |
| المصدر: | Chemistry Faculty Publications |
| بيانات النشر: | eCommons |
| سنة النشر: | 1995 |
| المجموعة: | University of Dayton: eCommons |
| مصطلحات موضوعية: | Analytical Chemistry, Biochemical Phenomena, Metabolism, and Nutrition, Chemical and Pharmacologic Phenomena, Chemistry, Environmental Chemistry, Inorganic Chemistry, Materials Chemistry, Medical Biochemistry, Medicinal-Pharmaceutical Chemistry, Organic Chemistry, Other Chemistry, Physical Chemistry |
| الوصف: | The solid-state structure of the compound of empirical formula P3Cl14Br, has been investigated by single-crystal and high-resolution powder diffraction techniques. The results of the structural study are correlated with the Raman spectra of P3Cl14Br and metastable PCl5. Refinement in tetragonal space group l4, with a= 8.739(2), c= 12.320(1)Å, Z= 2 and R= 0.058 yielded a structure composed of two PCl4+ tetrahedra of Cs symmetry, one PCl6– octahedron of C4vsymmetry, and one Br–. Rietveld refinement of powder data was carried out in l4 and l4/m. The Raman spectrum of the same crystal used for single crystal X-ray analysis was found to be strikingly similar to that of metastable PCl5 with vibrational degeneracies lifted. Metastable PCl5and P3Cl14Br are structurally very similar. |
| نوع الوثيقة: | text |
| اللغة: | unknown |
| العلاقة: | https://ecommons.udayton.edu/chm_fac_pub/61Test; http://dx.doi.org/10.1039/DT9950002719Test |
| DOI: | 10.1039/DT9950002719 |
| الإتاحة: | https://doi.org/10.1039/DT9950002719Test https://ecommons.udayton.edu/chm_fac_pub/61Test |
| رقم الانضمام: | edsbas.78239890 |
| قاعدة البيانات: | BASE |
| DOI: | 10.1039/DT9950002719 |
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