دورية أكاديمية
De-epimerizing DyKAT of β-Lactones Generated by Isothiourea-Catalysed Enantioselective [2+2] Cycloaddition
| العنوان: | De-epimerizing DyKAT of β-Lactones Generated by Isothiourea-Catalysed Enantioselective [2+2] Cycloaddition |
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| المؤلفون: | Conboy, Aífe, Goodfellow, Alister S., Kasten, Kevin, Dunne, Joanne, Cordes, David Bradford, Buehl, Michael, Smith, Andrew D |
| المصدر: | Chemical Science ; ISSN 2041-6520 2041-6539 |
| بيانات النشر: | Royal Society of Chemistry (RSC) |
| سنة النشر: | 2024 |
| الوصف: | Moderate diastereoselectivity (typically 70:30 dr) is observed in the isothiourea-catalysed [2+2]-cycloaddition of C(1)-ammonium enolates with pyrazol-4,5-diones to generate spirocyclic β lactones, but subsequent ring-opening with morpholine generatesβ hydroxyamide products with... |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | English |
| DOI: | 10.1039/d4sc01410c |
| الإتاحة: | https://doi.org/10.1039/d4sc01410cTest http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC01410CTest |
| حقوق: | http://creativecommons.org/licenses/by/3.0Test/ |
| رقم الانضمام: | edsbas.771EDE11 |
| قاعدة البيانات: | BASE |
| DOI: | 10.1039/d4sc01410c |
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