دورية
The levelling effect of solvational imbalances in the reactions of oximate α-nucleophiles with electrophilic phosphorus centers. Relevance to detoxification of organophosphorus esters
| العنوان: | The levelling effect of solvational imbalances in the reactions of oximate α-nucleophiles with electrophilic phosphorus centers. Relevance to detoxification of organophosphorus esters |
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| المؤلفون: | Terrier, F., Guével, E. Le, Chatrousse, A. P., Moutiers, G., Buncel, E. |
| المصدر: | Chemical Communications; February 20, 2003, Vol. 2003 Issue: 5 p600-601, 2p |
| مستخلص: | A study of the reactions of oximate α-nucleophiles with diisopropylphosphorofluoridate (DFP) and two model phosphonates, has revealed either a levelling-off in reactivity or a bell-shaped behaviour in accordance with a critical decoupling of desolvation and bond formation (solvational imbalances); the relevance of these results to detoxification is emphasized. |
| قاعدة البيانات: | Supplemental Index |
| تدمد: | 13597345 1364548X |
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