Selectivity switching resulting in the formation of benzene by surface carbonates on ceria in catalytic gas-phase oxidation of benzyl alcohol
| العنوان: | Selectivity switching resulting in the formation of benzene by surface carbonates on ceria in catalytic gas-phase oxidation of benzyl alcohol |
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| المؤلفون: | Jie Fan, Xin Ping Wu, Yu Tang, Yihu Dai, Xue-Qing Gong, Yanhui Yang |
| المصدر: | Chemical Communications. 52:2827-2830 |
| بيانات النشر: | Royal Society of Chemistry (RSC), 2016. |
| سنة النشر: | 2016 |
| مصطلحات موضوعية: | Inorganic chemistry, Decarbonylation, Metals and Alloys, 02 engineering and technology, General Chemistry, 010402 general chemistry, 021001 nanoscience & nanotechnology, Photochemistry, 01 natural sciences, Catalysis, Spectral line, 0104 chemical sciences, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials, Benzaldehyde, chemistry.chemical_compound, chemistry, Benzyl alcohol, Materials Chemistry, Ceramics and Composites, Carbonate, 0210 nano-technology, Selectivity, Benzene |
| الوصف: | The irreversible formation of carbonate deposits on CeO2 leads to complete switching of catalytic selectivity resulting in the formation of benzene in gas-phase oxidation of benzyl alcohol. By integrating experimental spectra and theoretical calculations, we expect that such a shift is derived from further decarbonylation of benzaldehyde via easy trapping of CO fragments by surface carbonate species. |
| تدمد: | 1364-548X 1359-7345 |
| الوصول الحر: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0ac60e0cfaabdbcfe9deb727444f7423Test https://doi.org/10.1039/c5cc08904bTest |
| رقم الانضمام: | edsair.doi.dedup.....0ac60e0cfaabdbcfe9deb727444f7423 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 1364548X 13597345 |
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