التفاصيل البيبلوغرافية
| العنوان: |
Lithium Bromide/HBpin: A Mild and Effective Catalytic System for the Selective Hydroboration of Aldehydes and Ketones. |
| المؤلفون: |
Kim, Hanbi1 (AUTHOR), Shin, Hye Lim1 (AUTHOR), Yi, Jaeeun1 (AUTHOR), Choi, Hyeon Seong1 (AUTHOR), Lee, Ji Hye1 (AUTHOR), Hwang, Hyonseok1 (AUTHOR), An, Duk Keun1 (AUTHOR) dkan@kangwon.ac.kr |
| المصدر: |
Bulletin of the Korean Chemical Society. Oct2020, Vol. 41 Issue 10, p1009-1018. 10p. |
| مصطلحات موضوعية: |
*HYDROBORATION, *KETONES, *ALDEHYDES, *BROMIDES, *ALKALI metal ions |
| مستخلص: |
The catalytic hydroboration of aldehydes and ketones with HBpin was examined using simple and commercially available metal salts (Li, Na, and K). Among the tested salts, LiBr (0.5–1.0 mol%) was found to be an efficient catalyst for the hydroboration of various aldehydes and ketones at room temperature. Further, the chemoselective hydroboration of aldehydes over ketones was also demonstrated. [ABSTRACT FROM AUTHOR] |
| قاعدة البيانات: |
Academic Search Index |
