التفاصيل البيبلوغرافية
| العنوان: |
Cobalt-Catalyzed Z-Selective Hydrosilylation of Terminal Alkynes. |
| المؤلفون: |
Teo, Wei Jie, Wang, Chao, Tan, Ye Wei, Ge, Shaozhong |
| المصدر: |
Angewandte Chemie International Edition; 4/3/2017, Vol. 56 Issue 15, p4328-4332, 5p |
| مصطلحات موضوعية: |
COBALT catalysts, HYDROSILYLATION, ALKYNES, VINYLSILANES, PHENOL, ISOMERIZATION |
| مستخلص: |
A cobalt-catalyzed Z-selective hydrosilylation of alkynes has been developed relying on catalysts generated from bench-stable Co(OAc)2 and pyridine-2,6-diimine (PDI) ligands. A variety of functionalized aromatic and aliphatic alkynes undergo this transformation, yielding Z-vinylsilanes in high yields with excellent selectivities ( Z/ E ratio ranges from 90:10 to >99:1). The addition of a catalytic amount of phenol effectively suppressed the Z/ E-isomerization of the Z-vinylsilanes that formed under catalytic conditions. [ABSTRACT FROM AUTHOR] |
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| قاعدة البيانات: |
Complementary Index |
