Anodic Stripping Voltammetric Determination of Mercury in Water Using a Chitosan‐Modified Carbon Paste Electrode
| العنوان: | Anodic Stripping Voltammetric Determination of Mercury in Water Using a Chitosan‐Modified Carbon Paste Electrode |
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| المؤلفون: | Luiz H. Marcolino-Junior, Bruna C. Lourencao, Orlando Fatibello-Filho, Bruno C. Janegitz |
| المصدر: | Analytical Letters. 40:3119-3128 |
| بيانات النشر: | Informa UK Limited, 2007. |
| سنة النشر: | 2007 |
| مصطلحات موضوعية: | Detection limit, Horizontal scan rate, Chemistry, Supporting electrolyte, Biochemistry (medical), Clinical Biochemistry, Analytical chemistry, Electrochemistry, Biochemistry, Analytical Chemistry, Chitosan, Anodic stripping voltammetry, chemistry.chemical_compound, Electrode, Graphite, Spectroscopy, Nuclear chemistry |
| الوصف: | This paper describes the preparation and electrochemical application of a modified carbon paste electrode with chitosan for the determination of Hg(II) ions in water using anodic stripping voltammetry. Experimental parameters, including the pH of the supporting electrolyte, time and potential of accumulation and scan rate were investigated. The best voltammetric response was observed for a paste composition of 60% (m/m) of graphite powder, 20% (m/m) of chitosan and 20% (m/m) of mineral oil, with 0.1 mol/l NaNO3 solution at pH 6.3 as supporting electrolyte, a preconcentration potential of −0.2 V, preconcentration time of 270 s and a scan rate of 25 mV/s. Under these optimal experimental conditions, the voltammetric signals were linearly dependent on the Hg(II) concentration in the range of 9.99×10−7 to 3.85×10−5 mol/l with a detection limit of 6.28×10−7 mol/l. Three “spiked” samples of water were evaluated using the proposed sensor, and results agreed with those obtained by a reference method at ... |
| تدمد: | 1532-236X 0003-2719 |
| الوصول الحر: | https://explore.openaire.eu/search/publication?articleId=doi_________::c08ddb79822033c13a47de2c69b2cd97Test https://doi.org/10.1080/00032710701645463Test |
| رقم الانضمام: | edsair.doi...........c08ddb79822033c13a47de2c69b2cd97 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 1532236X 00032719 |
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