دورية أكاديمية

Expanding the portfolio of tribo-positive materials: aniline formaldehyde condensates for high charge density triboelectric nanogenerators

التفاصيل البيبلوغرافية
العنوان: Expanding the portfolio of tribo-positive materials: aniline formaldehyde condensates for high charge density triboelectric nanogenerators
المؤلفون: Zhao, Pengfei, Soin, Navneet, Kumar, Amit, Shi, Lin, Guan, Shaoliang, Tsonos, Christos, Yu, Zidong, Ray, Sekhar Chandra, McLaughlin, James, Zhu, Zhigang, Zhou, Erping, Geng, Junfeng, See, Chan H., Luo, Jikui
المصدر: Zhao , P , Soin , N , Kumar , A , Shi , L , Guan , S , Tsonos , C , Yu , Z , Ray , S C , McLaughlin , J , Zhu , Z , Zhou , E , Geng , J , See , C H & Luo , J 2020 , ' Expanding the portfolio of tribo-positive materials: aniline formaldehyde condensates for high charge density triboelectric nanogenerators ' , Nano Energy , vol. 67 , no. 104291 , 104291 . https://doi.org/10.1016/j.nanoen.2019.104291Test
سنة النشر: 2020
المجموعة: Queen's University Belfast: Research Portal
الوصف: The rapid uptake of energy harvesting triboelectric nanogenerators (TENGs) for self-powered electronics requires the development of high-performance tribo-materials capable of providing large power outputs. This work reports on the synthesis and use of aniline formaldehyde resin (AFR) for energy-harvesting applications. The facile, acidic-medium reaction between aniline and formaldehyde produces the aniline-formaldehyde condensate, which upon an in-vacuo high temperature curing step provides smooth AFR films with abundant positively-charged nitrogen and oxygen surface functional groups, endowing AFR with a significantly higher positive tribo-polarity than the existing state-of-art polyamide-6 (PA6). A TENG comprising of optimized thin-layered AFR against a polytetrafluoroethylene (PTFE) film produced a peak-to-peak voltage of up to ~1,000 V, a current density of ~65 mA m-2, a transferred charge density of ~200 μC m-2 and an instantaneous power output (energy pulse) of ~11 W m-2 (28.1 μJ cycle-1), respectively. The suitability of AFR was further supported through the scanning Kelvin probe force microscopy (SKPFM) measurements, which reveal a significantly higher surface potential value of 1.147 V for AFR as compared to 0.87 V for PA6 and a step-by-step increase of the surface potential with the increase of energy generation cycles. The work not only proposes a novel mouldable AFR synthesis process but also expands with excellent prospects, the current portfolio of tribo-positive materials for triboelectric energy harvesting applications.
نوع الوثيقة: article in journal/newspaper
وصف الملف: application/pdf
اللغة: English
العلاقة: https://pure.qub.ac.uk/en/publications/36f46062-4bba-44b1-96cd-277cc48c3325Test
DOI: 10.1016/j.nanoen.2019.104291
الإتاحة: https://doi.org/10.1016/j.nanoen.2019.104291Test
https://pure.qub.ac.uk/en/publications/36f46062-4bba-44b1-96cd-277cc48c3325Test
https://pureadmin.qub.ac.uk/ws/files/190861208/Revised_Aniline_Formaldehyde_Nano_Energy_NS_AK_V2.pdfTest
حقوق: info:eu-repo/semantics/openAccess
رقم الانضمام: edsbas.5B489A58
قاعدة البيانات: BASE