مورد إلكتروني
Palladium-Catalyzed Aerobic Anti-Markovnikov Oxidation of Aliphatic Alkenes to Terminal Acetals
| العنوان: | Palladium-Catalyzed Aerobic Anti-Markovnikov Oxidation of Aliphatic Alkenes to Terminal Acetals |
|---|---|
| بيانات النشر: | ACS Publications 2019-06-20 2019-01-21 |
| تفاصيل مُضافة: | Komori, Saki Yamaguchi, Yoshiko 1000090221879 Kataoka, Yasutaka Kataoka, Yasutaka 1000040335196 Ura, Yasuyuki Ura, Yasuyuki |
| نوع الوثيقة: | Electronic Resource |
| مستخلص: | type:Article This document is the unedited Author' s version of a Submitted Work that was subsequently accepted for publication in The Journal of Organic Chemistry, copyright "American Chemical Society" after peer review. To access the final edited and published work see "https://doi.org/10.1021/acs.joc.8b02919Test" Terminal acetals were selectively synthesized from various unbiased aliphatic terminal alkenes and 1,2-, 1,3-, or 1,4-diols using a PdCl2(MeCN)2/CuCl catalyst system in the presence of p-toluquinone under 1 atm of O2 and mild reaction conditions. The slow addition of terminal alkenes suppressed the isomerization to internal alkenes successfully. Electron-deficient cyclic alkenes, such as p-toluquinone, were key additives to enhance the catalytic activity and the anti-Markovnikov selectivity. The halogen groups in the alkenes were found to operate as directing groups, suppressing isomerization and increasing the selectivity efficiently. |
| مصطلحات الفهرس: | terminal acetals, aliphatic terminal alkenes, anti-Markovnikov Production, oxidation, Journal Article, AM |
| URL: | |
| الإتاحة: | Open access content. Open access content |
| ملاحظة: | application/pdf English |
| أرقام أخرى: | JPNII oai:irdb.nii.ac.jp:01138:0004072541 AA00704100 1520-6904 The Journal of Organic Chemistry, 84(6), 3093-3099 1375210696 |
| المصدر المساهم: | NATIONAL INST OF INFO From OAIster®, provided by the OCLC Cooperative. |
| رقم الانضمام: | edsoai.on1375210696 |
| قاعدة البيانات: | OAIster |
| الوصف غير متاح. |