التفاصيل البيبلوغرافية
| العنوان: |
Synthesis and Theoretical Studies of [2-amino-3-(ethoxycarbonyl)-1,4- dihydro-1-phenyl-4-pyridinyl] Ferrocene Derivatives. |
| المؤلفون: |
Shajari, Nahid, Ghiasi, Reza, Aghaei, Neda, Soltani, Mahsa, Kazemizadeh, Ali Reza |
| المصدر: |
International Journal of New Chemistry; 2020, Vol. 7 Issue 4, p283-295, 13p |
| مصطلحات موضوعية: |
FERROCENE derivatives, MASS spectrometry, FRONTIER orbitals, OPTICAL properties, ELECTROPHILES, BAND gaps |
| مستخلص: |
In this study, syntheses of [2-amino-3-(ethoxycarbonyl)-1,4-dihydro-1-phenyl-4-pyridinyl]ferrocene derivatives from reaction of ferrocenecarboxaldehyde, ethyl cyanoacetate, aniline, and acetylenic esters in the presence of piperidine were reported in good yields. The reaction proceeded smoothly and cleanly under mild reaction conditions and no side reactions were observed. The structures of the products were confirmed by IR, 1H NMR, 13C NMR, mass spectroscopy, and elemental analysis. Then, structure, electronic and spectroscopic properties of the synthesized molecules were computed at the CAM-B3LYP/jorge-DZP (H,C,N,O) and Def2-TZVPPD (Fe) level of theory. First hyperpolarizability value were calculated to describe the nonlinear optical (NLO) properties of these molecules. The HOMO-LUMO study to find the band gap of the prepared molecules was extended to calculate global hardness, chemical potential and global electrophilicity for the investigation of the chemical behavior of the compounds. The energies of iron d-orbitals and formal electron configurations of iron atom were calculated by natural bond orbital (NBO) analysis. [ABSTRACT FROM AUTHOR] |
|
Copyright of International Journal of New Chemistry is the property of International Journal of New Chemistry and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) |
| قاعدة البيانات: |
Complementary Index |
