دورية أكاديمية
High-efficiency synthesis of dendrimer-like poly(ethylene oxide) via “arm-first” approach
| العنوان: | High-efficiency synthesis of dendrimer-like poly(ethylene oxide) via “arm-first” approach |
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| المؤلفون: | Zhu, Saisai, Xia, Ru, Chen, Peng, Yang, Bin, Miao, Jibin, Zheng, Zhengzhi, Su, Lifeng, Qian, Jiasheng, Cao, Ming, Feng, Xiaoshuang |
| المساهمون: | Physical Science and Engineering (PSE) Division, Key Laboratory of Environment-Friendly Polymeric Materials of Anhui Province, School of Chemistry and Chemical Engineering, Anhui University, Hefei, People’s Republic of China |
| بيانات النشر: | Springer Nature |
| سنة النشر: | 2017 |
| المجموعة: | King Abdullah University of Science and Technology: KAUST Repository |
| مصطلحات موضوعية: | Dendrimer-like poly(ethylene oxide), Arm-first, Anionic ring-opening polymerization, Click chemistry |
| الوصف: | In this study, a dendrimer-like polymer based on poly(ethylene oxide) (PEO) was synthesized through a combination of anionic ring-opening polymerization (AROP) and click reaction via arm-first method. Firstly, the polymeric arm, a linear PEO with one alkynyl group and two bromo groups, was synthesized by AROP of ethylene oxide followed by functionalization with propargyl bromide and esterified with 2-bromopropionic bromide. Second, a star PEO carrying three azide groups was synthesized though AROP of ethylene oxide used 1,1,1-tris(hydrosymethyl) ethane as initiator followed esterificated with 2-bromopropionic acid and azidation. By azide–alkyne click reactions between the azide-terminated PEO star polymer and linear PEO with functionalization alkynyl group, a three generation dendrimer-like PEO, G3-PEO-24Br, was successfully synthesized. The resulting polymers were observed to have precisely controlled molecular weights and compositions with narrow molecular weight distributions. ; This work was supported by the National Natural Science Foundation of China (No. 21174001 and No. 51403001), the “211 Project” of the Anhui University (No. J01001319), and the Research Foundation of the College of Chemistry and Chemical Engineering of Anhui University. The authors acknowledge the support from the “Institute of High Performance Rubber Materials & Products” (Hefei) and |
| نوع الوثيقة: | article in journal/newspaper |
| اللغة: | unknown |
| تدمد: | 1022-9760 1572-8935 |
| العلاقة: | http://link.springer.com/article/10.1007%2Fs10965-017-1213-8Test; Zhu S, Xia R, Chen P, Yang B, Miao J, et al. (2017) High-efficiency synthesis of dendrimer-like poly(ethylene oxide) via “arm-first” approach. Journal of Polymer Research 24. Available: http://dx.doi.org/10.1007/s10965-017-1213-8Test.; Journal of Polymer Research; http://hdl.handle.net/10754/623841Test |
| DOI: | 10.1007/s10965-017-1213-8 |
| الإتاحة: | https://doi.org/10.1007/s10965-017-1213-8Test http://hdl.handle.net/10754/623841Test |
| رقم الانضمام: | edsbas.2B196127 |
| قاعدة البيانات: | BASE |
| تدمد: | 10229760 15728935 |
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| DOI: | 10.1007/s10965-017-1213-8 |