دورية أكاديمية

Degradation of Structurally Defined Graphene Nanoribbons by Myeloperoxidase and the Photo-Fenton Reaction

التفاصيل البيبلوغرافية
العنوان: Degradation of Structurally Defined Graphene Nanoribbons by Myeloperoxidase and the Photo-Fenton Reaction
المؤلفون: Luan X., Martin C., Zhang P., Li Q., Vacchi I. A., Delogu L. G., Mai Y., Bianco A.
المساهمون: Luan, X., Martin, C., Zhang, P., Li, Q., Vacchi, I. A., Delogu, L. G., Mai, Y., Bianco, A.
بيانات النشر: Wiley-VCH Verlag
سنة النشر: 2020
المجموعة: Padua Research Archive (IRIS - Università degli Studi di Padova)
مصطلحات موضوعية: biodegradability, carbon material, hydroxyl radical, peroxidase, photo-Fenton reaction
الوصف: As an emerging member of the graphene family, structurally defined graphene nanoribbons (GNRs) have shown promising applications in various fields. The evaluation of the degradability of GNRs is particularly important for assessing the persistence level and risk of these materials in living organisms and the environment. However, there is a void in the study of the degradation of GNRs. Here, we report the degradation behavior of GNRs in the presence of human myeloperoxidase (hMPO) or treated with the photo-Fenton (PF) reaction. With the assistance of potassium hydroxide or imidazole, which facilitates the dispersion of GNRs in the aqueous solution, GNRs underwent only partial degradation after 25-hour incubation with hMPO, while, the PF reaction degraded GNRs almost completely after 120 hours. These results indicate that structurally precise GNRs can be efficiently degraded under suitable conditions, providing more opportunities for future applications in different fields.
نوع الوثيقة: article in journal/newspaper
اللغة: English
العلاقة: info:eu-repo/semantics/altIdentifier/pmid/32643814; info:eu-repo/semantics/altIdentifier/wos/WOS:000559994200001; journal:ANGEWANDTE CHEMIE. INTERNATIONAL EDITION; http://hdl.handle.net/11577/3352617Test; info:eu-repo/semantics/altIdentifier/scopus/2-s2.0-85089545003
DOI: 10.1002/anie.202008925
الإتاحة: https://doi.org/10.1002/anie.202008925Test
http://hdl.handle.net/11577/3352617Test
رقم الانضمام: edsbas.649C54BA
قاعدة البيانات: BASE