التفاصيل البيبلوغرافية
| العنوان: |
Controlling Oxidative Addition and Reductive Elimination at Tin(I) via Hemi‐Lability |
| المؤلفون: |
Aldridge, Simon, Caise, Alexa, Crumpton, Agamemnon E., Vasko, Petra, Hicks, Jamie, McManus, Caitilín, Rees, Nicholas H. |
| بيانات النشر: |
Wiley |
| سنة النشر: |
2022 |
| المجموعة: |
JYX - Jyväskylä University Digital Archive / Jyväskylän yliopiston julkaisuarkisto |
| مصطلحات موضوعية: |
tin, oxidative addition, reductive elimination, hemi-labile ligand, reversibility, ligandit, tina, orgaaniset tinayhdisteet, kemiallinen synteesi, kompleksiyhdisteet |
| الوصف: |
We report on the synthesis of a distannyne supported by a pincer ligand bearing pendant amine donors that is capable of reversibly activating E–H bonds at one or both of the tin centres through dissociation of the hemi-labile N–Sn donor/acceptor interactions. This chemistry can be exploited to sequentially (and reversibly) assemble mixed-valence chains of tin atoms of the type ArSn{Sn(Ar)H} n SnAr ( n = 1, 2). The experimentally observed (decreasing) propensity towards chain growth with increasing chain length can be rationalized both thermodynamically and kinetically by the electron-withdrawing properties of the –Sn(Ar)H– backbone units generated via oxidative addition. ; peerReviewed |
| نوع الوثيقة: |
article in journal/newspaper |
| وصف الملف: |
application/pdf; fulltext |
| اللغة: |
English |
| تدمد: |
1433-7851 |
| العلاقة: |
Angewandte Chemie; 61; 314794; Research Council of Finland; Suomen Akatemia; Aldridge, S., Caise, A., Crumpton, A. E., Vasko, P., Hicks, J., McManus, C., & Rees, N. H. (2022). Controlling Oxidative Addition and Reductive Elimination at Tin(I) via Hemi‐Lability. Angewandte Chemie , 61 (5), Article e202114926. https://doi.org/10.1002/anie.202114926Test; CONVID_101984985; URN:NBN:fi:jyu-202111295822; http://urn.fi/URN:NBN:fi:jyu-202111295822Test |
| الإتاحة: |
http://urn.fi/URN:NBN:fi:jyu-202111295822Test |
| حقوق: |
In Copyright ; © 2021 Wiley-VCH GmbH ; openAccess ; http://rightsstatements.org/page/InC/1.0/?language=enTest |
| رقم الانضمام: |
edsbas.AE547B2E |
| قاعدة البيانات: |
BASE |
