دورية أكاديمية
Observing femtosecond fragmentation using ultrafast X-ray-induced auger spectra
| العنوان: | Observing femtosecond fragmentation using ultrafast X-ray-induced auger spectra |
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| المؤلفون: | Wolf, Thomas J. A., Holzmeier, Fabian, Wagner, Isabella, Berrah, Nora, Bostedt, Christoph, Bozek, John, Bucksbaum, Phil, Coffee, Ryan, Cryan, James, Farrell, Joe, Feifel, Raimund, Martinez, Todd J., McFarland, Brian, Mucke, Melanie, Nandi, Saikat, Tarantelli, Francesco, Fischer, Ingo, Gühr, Markus |
| المساهمون: | Wolf, Thomas J. A., Holzmeier, Fabian, Wagner, Isabella, Berrah, Nora, Bostedt, Christoph, Bozek, John, Bucksbaum, Phil, Coffee, Ryan, Cryan, Jame, Farrell, Joe, Feifel, Raimund, Martinez, Todd J., Mcfarland, Brian, Mucke, Melanie, Nandi, Saikat, Tarantelli, Francesco, Fischer, Ingo, Gühr, Markus |
| سنة النشر: | 2017 |
| المجموعة: | IRIS Università degli Studi di Perugia |
| مصطلحات موضوعية: | Auger electron spectroscopy, Photochemistry, Photofragmentation, Ultrafast dynamic, Materials Science (all), Instrumentation, Engineering (all), Process Chemistry and Technology, Computer Science Applications1707 Computer Vision and Pattern Recognition, Fluid Flow and Transfer Processes |
| الوصف: | Molecules often fragment after photoionization in the gas phase. Usually, this process can only be investigated spectroscopically as long as there exists electron correlation between the photofragments. Important parameters, like their kinetic energy after separation, cannot be investigated. We are reporting on a femtosecond time-resolved Auger electron spectroscopy study concerning the photofragmentation dynamics of thymine. We observe the appearance of clearly distinguishable signatures from thymine0s neutral photofragment isocyanic acid. Furthermore, we observe a time-dependent shift of its spectrum, which we can attribute to the influence of the charged fragment on the Auger electron. This allows us to map our time-dependent dataset onto the fragmentation coordinate. The time dependence of the shift supports efficient transformation of the excess energy gained from photoionization into kinetic energy of the fragments. Our method is broadly applicable to the investigation of photofragmentation processes. |
| نوع الوثيقة: | article in journal/newspaper |
| وصف الملف: | STAMPA |
| اللغة: | English |
| العلاقة: | info:eu-repo/semantics/altIdentifier/wos/WOS:000407700400038; volume:7; issue:7; firstpage:681; numberofpages:11; journal:APPLIED SCIENCES; http://hdl.handle.net/11391/1423487Test; info:eu-repo/semantics/altIdentifier/scopus/2-s2.0-85021624051; http://www.mdpi.com/2076-3417/7/7/681/pdfTest |
| DOI: | 10.3390/app7070681 |
| الإتاحة: | https://doi.org/10.3390/app7070681Test http://hdl.handle.net/11391/1423487Test http://www.mdpi.com/2076-3417/7/7/681/pdfTest |
| رقم الانضمام: | edsbas.71EA4B7E |
| قاعدة البيانات: | BASE |
| DOI: | 10.3390/app7070681 |
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