دورية أكاديمية
The synthesis of blue emitting 3-Amino-l-hetarylfluorenes and their unprecedented alkylated derivatives
| العنوان: | The synthesis of blue emitting 3-Amino-l-hetarylfluorenes and their unprecedented alkylated derivatives |
|---|---|
| المؤلفون: | Yalçın, Ergin, Duyar, Halil, Çakmaz, Deniz, Sahin, Ertan, Seferoğlu, Zeynel |
| المساهمون: | Mühendislik ve Doğa Bilimleri Fakültesi -- Mühendislik Temel Bilimleri Bölümü, Yalçın, Ergin |
| بيانات النشر: | Elsevier |
| سنة النشر: | 2019 |
| المجموعة: | DSpace@ISTE (Iskenderun Technical University Institutional Repository) |
| مصطلحات موضوعية: | 3-Amino-1-hetaryl-2,4-dicyanofluorenes, 3-Amino-1-hetarylfluorene derivatives, Decyanation reaction, Fluorescent dyes, Blue emitting fluorenes, Chemistry, Organic, Hydrogenation | Nitrobenzene Derivative | Nitro Compounds, Selective hydrogenation, Efficient synthesis, Fluorene, Arylidenemalonodinitriles, Nanoparticles, Reduction, Catalysts, Alcohols, Nitro, Alkylation, Carbon nuclear magnetic resonance, Chemical analysis, Chemical reaction, Fourier transform infrared spectroscopy, Nucleophilicity, Priority journal, Proton nuclear magnetic resonance, Quantum yield, Spectrofluorometry, Spectroscopy, Synthesis, Ultraviolet visible spectroscopy |
| الوصف: | WOS: 000485335600003 ; Novel 3-Amino-1-hetarylfluorene derivatives have medicinal uses and challenging transformation in organic synthesis have been synthesized via decyanation process. Surprisingly, the alkylated compounds derived from 3-Amino-1-hetarylfluorenes were obtained via further nucleophilic substitution to the 9-C and 3-N positions of the fluorene ring because of the harsh reaction condition employed. The synthesized compounds were characterized by spectroscopic techniques as well as X-ray single crystal diffraction analysis. This new family of blue emitting fluorene derivatives have low to moderate quantum yields (the largest value of Phi(F) = 0.52 for compound 15). (C) 2019 Elsevier Ltd. All rights reserved. ; Scientific and Technological Research Council of Turkey (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [113Z704] ; This research was supported by The Scientific and Technological Research Council of Turkey (TUBITAK) Grant no: 113Z704. |
| نوع الوثيقة: | article in journal/newspaper |
| وصف الملف: | application/pdf |
| اللغة: | English |
| تدمد: | 0040-4020 |
| العلاقة: | Tetrahedron; Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı; Web of Science - Scopus; Web of Science Core Collection - Science Citation Index Expanded; Web of Science Core Collection - Index Chemicus; https://doi.org/10.1016/j.tet.2019.130464Test; https://hdl.handle.net/20.500.12508/1196Test; 75; 35 |
| DOI: | 10.1016/j.tet.2019.130464 |
| الإتاحة: | https://doi.org/20.500.12508/1196Test https://doi.org/10.1016/j.tet.2019.130464Test https://hdl.handle.net/20.500.12508/1196Test |
| حقوق: | info:eu-repo/semantics/closedAccess |
| رقم الانضمام: | edsbas.FD7DF06B |
| قاعدة البيانات: | BASE |
| تدمد: | 00404020 |
|---|---|
| DOI: | 10.1016/j.tet.2019.130464 |