التفاصيل البيبلوغرافية
| العنوان: |
Crystal Facet and Architecture Engineering of Metal Oxide Nanonetwork Anodes for High-Performance Potassium Ion Batteries and Hybrid Capacitors |
| المؤلفون: |
Chao-Hung Chang (11895676), Kuan-Ting Chen (1605493), Yi-Yen Hsieh (9749434), Che-Bin Chang (10521053), Hsing-Yu Tuan (1453711) |
| سنة النشر: |
2022 |
| المجموعة: |
Smithsonian Institution: Digital Repository |
| مصطلحات موضوعية: |
Medicine, Molecular Biology, Physiology, Space Science, Biological Sciences not elsewhere classified, Chemical Sciences not elsewhere classified, sup >+, inherent insulating property, full cell configuration, enhance electrical conductivity, wide band gaps, functional anode candidates, extensive energy storage, alloying mechanism based, potassium ion batteries, stable dual conversion, 4 , 3 , 2 , report crystal facet, ternary metal oxides, metal oxides, wide range, storage performance, prospective dual, nanonetwork anode, crystal facet, binary conversion, alloying reactions, sub >< |
| الوصف: |
Metal oxides are considered as prospective dual-functional anode candidates for potassium ion batteries (PIBs) and hybrid capacitors (PIHCs) because of their abundance and high theoretic gravimetric capacity; however, due to the inherent insulating property of wide band gaps and deficient ion-transport kinetics, metal oxide anodes exhibit poor K + electrochemical performance. In this work, we report crystal facet and architecture engineering of metal oxides to achieve significantly enhanced K + storage performance. A bismuth antimonate (BiSbO 4 ) nanonetwork with an architecture of perpendicularly crossed single crystal nanorods of majorly exposed (001) planes are synthesized via CTAB-mediated growth. (001) is found to be the preferential surface diffusion path for superior adsorption and K + transport, and in addition, the interconnected nanorods gives rise to a robust matrix to enhance electrical conductivity and ion transport, as well as buffering dramatic volume change during insertion/extraction of K + . Thanks to the synergistic effect of facet and structural engineering of BiSbO 4 electrodes, a stable dual conversion-alloying mechanism based on reversible six-electron transfer per formula unit of ternary metal oxides is realized, proceeding by reversible coexistence of potassium peroxide conversion reactions (KO 2 ↔K 2 O) and Bi x Sb y alloying reactions (BiSb ↔ KBiSb ↔ K 3 BiSb). As a result, BiSbO 4 nanonetwork anodes show outstanding potassium ion storage in terms of capacity, cycling life, and rate capability. Finally, the implementation of a BiSbO 4 nanonetwork anode in the state-of-the-art full cell configuration of both PIBs and PIHCs shows satisfactory performance in a Ragone plot that sheds light on their practical applications for a wide range of K + -based energy storage devices. We believe this study will propose a promising avenue to design advanced hierarchical nanostructures of ternary or binary conversion-type materials for PIBs, PIHCs, or even for extensive energy storage. |
| نوع الوثيقة: |
article in journal/newspaper |
| اللغة: |
unknown |
| العلاقة: |
https://figshare.com/articles/journal_contribution/Crystal_Facet_and_Architecture_Engineering_of_Metal_Oxide_Nanonetwork_Anodes_for_High-Performance_Potassium_Ion_Batteries_and_Hybrid_Capacitors/17738359Test |
| DOI: |
10.1021/acsnano.1c09863.s001 |
| الإتاحة: |
https://doi.org/10.1021/acsnano.1c09863.s001Test |
| حقوق: |
CC BY-NC 4.0 |
| رقم الانضمام: |
edsbas.F04B2CF7 |
| قاعدة البيانات: |
BASE |
